Везде

RAS PresidiumВестник Дальневосточного отделения Российской академии наук Vestnik of the Far East Branch of the Russian Academy of Sciences

  • ISSN (Print) 0869-7698
  • ISSN (Online) 3034-5308

Electrochemical formation of polymer/gold and platinum nanoparticle nanocomposites

You can
PII
S3034530825040047-1
DOI
10.7868/S3034530825040047
Publication type
Article
Status
Published
Authors
L.G. Kolzunova
  • Occupation: Doctor of Sciences in Chemistry, Chief Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
E.V. Shchitovskaya
  • Occupation: Candidate of Sciences in Chemistry, Senior Researcher; Associate Professor
  • Affiliation:
    Institute of Chemistry, FEB RAS
    Far Eastern Federal University
V.G. Emelyanova
  • Occupation: Laboratory Research Assistant; Master's Student
  • Affiliation:
    Institute of Chemistry, FEB RAS
    Far Eastern Federal University
V. S. Egorkin
  • Occupation: Candidate of Sciences in Chemistry, Head of Laboratory
  • Affiliation: Institute of Chemistry, FEB RAS
Volume/ Edition
Volume / Issue number 4
Pages
40-53
Abstract
The mechanism of electrochemical formation of a nanocomposite based on polymethylolacrylamide with inclusion of gold and platinum nanoparticles was studied using chronoamperometry and impedance spectroscopy. It was found that the process is complex and includes electrochemical (formation of radicals, synthesis of AuNPs and PtNPs nanoparticles, electrodeposition of a Zn sublayer) and chemical (initiation of polymerization and formation of a polymer layer, inclusion of nanoparticles into the polymer matrix) stages occurring simultaneously for 5–10 minutes. It was found that as a result of these processes, the electrode capacitance passes through a maximum, and the resistance increases, which is associated with both the deposition of a new crystalline phase on the cathode and the insulating effect of the polymer. The inclusion of metal nanoparticles in the film increases the electrical conductivity of the nanocomposite.
Keywords
нанокомпозиты электрополимеризация полиметилолакриламид наночастицы платины наночастицы золота
Date of publication
21.08.2025
Year of publication
2025
Number of purchasers
0
Views
52

References

  1. 1. Sahu S.K., Boggarapu V., Sreekanth P.S.R. Improvements in the mechanical and thermal characteristics of polymer matrix composites reinforced with various nanofillers: a brief review // Mater. Today. 2024. Vol. 113. P. 1–8.
  2. 2. Sahu S.K., Badgayan N.D., Samanta S., Sreekanth P.S.R. Quasistatic and dynamic nanomechanical properties of HDPE reinforced with 0/1/2 dimensional carbon nanofillers based hybrid nanocomposite using nanoindentation // Mater. Chem. Phys. 2018. Vol. 203. P. 173–184.
  3. 3. Badgayan N.D., Sahu S.K., Samanta S., Sreekanth P.S.R. An insight into mechanical properties of polymer nanocomposites reinforced with multidimensional filler system: a state of art review // Mater. Today. Proc. 2020. Vol. 24. P. 422–431.
  4. 4. Yang X., Li S., Yang Y., Huang X., Huang X., Li L., Yang W., Zhang Z., Shen G., Hou X., Cui Q., Chen A. Novel AuNPs/Fe–MOF based molecularly imprinted electrochemical sensors for detection of hydroxy-α-sanshool and hydroxy-(α+β)-sanshool in Zanthoxylumbungeanum Maxim and its processed products // Microchem. J. 2025. Vol. 209. P. 112873.
  5. 5. Al-Ghamdi Y.O., Saeed G., Ali M., Ali K. Polymers blended peanuts activated carbon composite hydrogels fabricated AgNPs as dip-catalyst for industrial dyes discoloration in aqueous medium // Ind. Crops Prod. 2022. Vol. 188. P. 115588.
  6. 6. Pattadakal S., Ghatti V., Chapi S., Vidya G., Kumarswamy Y.K.; Raghu M.S., Vidyavathi G.T., Nandihalli N., Kasai D.R. Poly(vinyl alcohol) Nanocomposites Reinforced with CuO Nanoparticles Extracted by Ocimum sanctum: Evaluation of Wound-Healing Applications // Polymers. 2025. Vol. 17. P. 400.
  7. 7. Chumachenko V., Kutsevol N., Rawiso M., Schmutz M., Blanck C. In situ formation of silver nanoparticles in linear and branched polyelectrolyte matrices using various reducing agents // Nanoscale Research Lett. 2014. Vol. 9. P. 164.
  8. 8. Tang E., Cheng G., Pang X., Ma X., Xing F. Synthesis of nano-ZnO/poly(methyl methacrylate) composite microsphere through emulsion polymerization and its UV-shielding property // Colloid Polym. Sci. 2006. Vol. 284, No. 4. P. 422–428.
  9. 9. Alkayal N.S. Fabrication of Cross-Linked PMMA/SnO2 Nanocomposites for Highly Efficient Removal of Chromium(III) from Wastewater // Polymers. 2022. Vol. 14, No. 10. P. 2101.
  10. 10. Mourato A., Wong S.M., Siegenthaler H., Abrantes L.M. Polyaniline films containing palladium microparticles for electrocatalytic purposes // J. Solid State Electrochem. 2006. Vol. 10, No. 3. P. 140–147.
  11. 11. Pei X., Liu J., Zhang Y., Huang Y., Li Z., Niu X., Zhang W., Sun W. Tetrahedral DNA-linked aptamer-antibody-based sandwich-type electrochemical sensor with Ag@Au core-shell nanoparticles as a signal amplifier for highly sensitive detection of α-fetoprotein // Microchim. Acta. 2024. Vol. 191. P. 414.
  12. 12. Щитовская Е.В., Карпенко М.А., Колзунова Л.Г., Сарин С.А. Электрохимическое включение частиц золота в непроводящую полиметилолакриламидную пленку // Вестн. ДВО РАН. 2017. № 6. С. 75–80.
  13. 13. Колзунова Л.Г., Щитовская Е.В., Карпенко М.А., Родзик И.Г. Потенциостатическое формирование композита полимер/наночастицы серебра // Вестн. ДВО РАН. 2020. № 1. С. 26–31.
  14. 14. Щитовская Е.В., Колзунова Л.Г., Курявый В.Г., Слободюк А.Б. Электрохимическое формирование и свойства полиметилолакриламидной пленки с включением частиц платины // Электрохимия. 2015. Т. 51, № 12. С. 1235–1246.
  15. 15. Колзунова Л.Г., Рунов А.К., Щитовская Е.В. Способ получения композитного материала, обладающего фотокаталитическими свойствами: пат. 2690378 (Россия). 2019.
  16. 16. Kolzunova L.G., Shchitovskaya E.V. Single-Step Electrochemical Synthesis of Composite Polymethylolacrylamide/Ultrafine Polytetrafluoroethylene // Russ. J. Electrochem. 2023. Vol. 59, No. 10. P. 774–786.
  17. 17. Karabiberoğlu Ş., Dursun Z. Au–Pt bimetallic nanoparticles anchored on conducting polymer: An effective electrocatalyst for direct electrooxidation of sodium borohydride in alkaline solution // Mater. Sci. Eng.: B. 2023. Vol. 288. P. 116158.
  18. 18. Han C., Li H., Zhao B., Chen M. Ultrasensitive electrochemical detection of miDNA-21 in human serum based on synergistic signal amplification by conducting polymers and bimetallic nanoparticles // Microchem. J. 2024. Vol. 207. P. 111956.
  19. 19. Sevcik J., Urbanek P., Skoda D., Jamatia T. Energy resolved-electrochemical impedance spectroscopy investigation of the role of Al-doped ZnO nanoparticles in electronic structure modification of polymer nanocomposite LEDs // Mater. Des. 2021. Vol. 205. P. 109738.
  20. 20. Hallemans N., Howey D., Battistel A., Saniee N.F. Electrochemical impedance spectroscopy beyond linearity and stationarity: a critical review // Electrochim. Acta. 2023. Vol. 466. P. 142939.
  21. 21. Ribeiro J.A., Jorge P. Applications of electrochemical impedance spectroscopy in disease diagnosis: a review // Sens. Actuators, B. 2024. Vol. 8. P. 100205.
  22. 22. Jimenez-Perez R., Agrisuelas J., Gomis-Berenguer A., Baeza-Romero M. One-pot electrodeposition of multilayered 3D PtNi/polymer nanocomposite. H2O2 determination in aerosol phase // Electrochim. Acta. 2023. Vol. 461. P. 142683.
  23. 23. Wang X., Koirala S., Xu L., Li Q. Insights in emerging Ti3C2TxMXene-enriched polymeric coatings for metallic surface protection: Advancements in microstructure, anti-aging, and electrochemical performance // Prog. Org. Coat. 2024. Vol. 194. P. 108606.
  24. 24. Dai H., Zhang S., Wei J., Jiao T. A self-powered photoelectrochemical aptasensing platform for microcystin-LR cathodic detection via integrating Bi2S3 CuInS2 photocathode // Sens. Actuators, B. Chem. 2023. Vol. 397. P. 134692.
  25. 25. Barsoukov E., Macdonald J.R. Impedance spectroscopy: theory, experiment and application. Second edition. N. Y.: Wiley, 2005. 595 p.
  26. 26. Grabovsky Y., Guynee J. A theory of inductive loops in electrochemical impedance spectroscopy. 2023. https://doi.org/10.48550/arXiv.2301.05024
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library