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RAS PresidiumВестник Дальневосточного отделения Российской академии наук Vestnik of the Far East Branch of the Russian Academy of Sciences

  • ISSN (Print) 0869-7698
  • ISSN (Online) 3034-5308

New glasses in the MNbOF5-BaF2-InF3 (M–Mn, Cd, Zn) systems

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PII
10.31857/S0869769824060125-1
DOI
10.31857/S0869769824060125
Publication type
Review
Status
Published
Authors
L. N. Ignatieva
  • Occupation: Doctor of Sciences in Chemistry, Chief Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
N. N. Savchenko
  • Occupation: Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
Yu. V. Marchenko
  • Occupation: Candidate of Sciences in Chemistry, Senior Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
V. А. Mashchenko
  • Occupation: Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
S. A. Sarin
  • Occupation: Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
Volume/ Edition
Volume / Issue number 6
Pages
187-202
Abstract
The article summarizes the results of studying new glasses in the MnNbOF5-BaF2-InF3, ZnNbOF5-BaF2-InF3 and CdNbOF5-BaF2-InF3 systems. The thermal characteristics of glasses were studied, the role of fluorindate and fluoroniobate components in glass formation and crystallization behavior was revealed. Glasses in the MNbOF5-BaF2-InF3 systems can be considered three-component; their structure is formed by polyhedra of fluoroniobate (NbO2F4 and NbO3F3), InF6 and polyhedra formed by MFn. The possibility of obtaining glass ceramics has been demonstrated. For glasses in the CdNbOF5-BaF2-InF3 and ZnNbOF5-BaF2-InF3 systems, the photoluminescence was detected corresponding to emission levels of 542, 573 and 673, 751 nm, depending on the presence and concentration of indium trifluoride in the glass. Luminescent properties are shown only by glasses in which nanoparticles, 9–13 nm, were detected according to SAXS data.
Keywords
стекла структура кристаллизация люминесценция стеклокерамика
Date of publication
05.12.2024
Year of publication
2024
Number of purchasers
0
Views
51

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