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RAS PresidiumВестник Дальневосточного отделения Российской академии наук Vestnik of the Far East Branch of the Russian Academy of Sciences

  • ISSN (Print) 0869-7698
  • ISSN (Online) 3034-5308

Structural chemistry of tetrachloride complexes of uranyl (review)

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PII
S30345308S0869769825020127-1
DOI
10.7868/S3034530825020127
Publication type
Review
Status
Published
Authors
R.L. Davidovich
  • Occupation: Doctor of Sciences in Chemistry, Professor, Chief Researcher
  • Affiliation: Institute of Chemistry, FEB RAS
Volume/ Edition
Volume / Issue number 2
Pages
156-174
Abstract
The crystal structures of tetrachloride complexes of uranyl with cations of alkali metals, and ammonium, protonated cations of organic bases, ammonium derivatives and a number of protonated organic compounds studied by single-crystal X-ray diffraction analysis are systematized and discussed. The crystal chemical features of the structure of this class of compounds have been determined. In the investigated crystal structures of UO22+ tetrachloride complexes, the coordination polyhedron of the hexavalent uranium atom has a tetragonal-bipyramidal (distorted octahedral) structure with oxygen atoms of the uranyl group located at the apical vertices of the tetragonal-bipyramidal polyhedron. The UO22+ groups in the coordination polyhedra are directed perpendicular to the equatorial plane, at the vertices of which four Cl atoms of coordinated ligands are located. In the presence in the structures of uranyl tetrachloride complexes, along with complex anions [UO2Cl4]2- and protonated cations, free Cl- ions and free, not associated with the U atom, neutral or coordinated molecules, containing acceptor atoms, the cations do not interact with the donor atoms of the Cl- anion, and form hydrogen bonds with the free chlorine ions and acceptor atoms of the free molecules. Due to the high symmetry (almost D4h) of the complex anion in the structures of tetrachloride complexes of uranyl, the compounds have been widely used for numerous physical studies, in particular spectroscopic, luminescence, functional density theory and others.
Keywords
тетрахлорид комплекс уранил кристаллическая структура катион рентгеноструктурный анализ
Date of publication
01.04.2025
Year of publication
2025
Number of purchasers
0
Views
53

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