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RAS PresidiumВестник Дальневосточного отделения Российской академии наук Vestnik of the Far East Branch of the Russian Academy of Sciences

  • ISSN (Print) 0869-7698
  • ISSN (Online) 3034-5308

Electron paramagnetic resonance on impurity copper ions in sodium trititanate with a hierarchical two-level architecture

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PII
10.31857/S0869769824010099-1
DOI
10.31857/S0869769824010099
Publication type
Article
Status
Published
Authors
Denis A. Saritsky
  • Occupation: Junior Researcher
  • Affiliation: Institute of Chemistry FEB RAS
Albert M. Ziatdinov
  • Occupation: Doctor of Sciences in Physics and Mathematics, Chief Researcher, Head of the Laboratory
  • Affiliation: Institute of Chemistry FEB RAS
Veniamin V. Zheleznov
  • Occupation: Doctor of Sciences in Chemistry, Leading Researcher
  • Affiliation: Institute of Chemistry FEB RAS
Denis P. Opra
  • Occupation: Candidate of Sciences in Chemistry, Senior Researcher, Head of the Laboratory
  • Affiliation: Institute of Chemistry FEB RAS
Sergey V. Gnedenkov
  • Occupation: Corresponding Member of the RAS, Doctor of Sciences in Chemistry, Professor, Director
  • Affiliation: Institute of Chemistry FEB RAS
Volume/ Edition
Volume / Issue number 1
Pages
126-143
Abstract
The results of studies of electron paramagnetic resonance on impurity copper ions in sodium trititanate (Na2Ti3O7) with a hierarchical two-level architecture, potentially suitable for use as negative electrodes of sodium-ion batteries, are presented. The main emphasis in the work was placed on the identification of magnetically different centers of the impurity copper ion, establishing the positions of these centers in the crystal lattice, determining the nature of their distributions in the volume of the sample, and elucidating the charge compensation mechanism for aliovalent substitutions. For Cu2+ ions in positions of Ti4+ substitution, the degree of a spin density delocalization from the bottom orbital to the σ-orbitals of the nearest equatorial oxygen ions was estimated.
Keywords
электронный парамагнитный резонанс трититанат натрия Cu2+ зарядовая компенсация молекулярные орбитали
Date of publication
15.09.2025
Year of publication
2025
Number of purchasers
0
Views
13

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